期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 17, 期 44, 页码 12294-12301出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201102348
关键词
chirality; gold; metallocorroles; NMR spectroscopy; X-ray diffraction
资金
- DFG
Corrole complexes with gold(I) and gold(III) were synthesized and their structural, photophysical, and electrochemical properties investigated. This work includes the X-ray crystallography characterization of gold(I) and gold(III) complexes, both chelated by a corrole with fully brominated beta-pyrrole carbon atoms. The mononuclear and chiral gold(I) corrole appears to be the first of its kind within the porphyrinoid family, while the most unique property of the gold(III) corrole is that it displays phosphorescence at ambient temperatures.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据