期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 17, 期 12, 页码 3500-3511出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201002765
关键词
annulenes; aromaticity; isomerization; porphyrinoids; tellurium
资金
- Ministry of Science and Higher Education [N204 013536]
An annulene-porphyrin hybrid, the diaaza-deficient porphyrin 5,10,15,20-tetraaryl-21,23-divacataporphyrin, has been synthesized by an extrusion of tellurium atom(s) from 5,10,15,20-tetraaryl-21,23-ditelluraporphyrin under treatment with HCl. In addition, a monoaza-deficient 5,10,15,20-tetraaryl-21-tellura-23-vacataporphyrin was formed in the same reaction. The two new members of the vacataporphyrin family were characterized by X-ray crystallography, as well as UV/Vis and NMR spectroscopy. These aromatic molecules preserve the fundamental structural and spectroscopic features of the parent tetraarylporphyrin. The X-ray crystal structures of 21,23-divacataporphyrin and 21-tellura-23-vacataporphyrin show typical porphyrin patterns. The molecules are not strictly planar and show distortion of the annulene moieties. The N22 center dot center dot center dot N24 distances (5.23 and 5.09 angstrom) are considerably longer than in regular porphyrins. For 21,23-divacataporphyrin, variable-temperature H-1 NMR spectroscopy data allowed the identification of divacataporphyrin stereoisomers differentiated by the geometry of the butadiene bridges. The forms remain in thermodynamic equilibrium.
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