期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 17, 期 50, 页码 14164-14169出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201102182
关键词
C-C coupling; electrochemistry; fluorinated compounds; oxidation; phenols
资金
- BASF SE
- Spin Centers (DFG) [SFB 813 Chemistry]
- Tokyo Institute of Technology
The direct and selective phenol coupling reaction that provides biphenols still represents a challenge in organic synthesis. The recently developed electrosynthesis on boron-doped diamond anodes with fluorinated additives was developed further to allow the application to less-expensive electrodes and fluorinated media. This advanced protocol allows the highly selective anodic phenol coupling reaction on graphite with a broad scope.
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