期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 17, 期 37, 页码 10350-10356出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201101174
关键词
C-C coupling; condensation; olefination; palladium; stilbenoids
资金
- C.S.I.R., New Delhi
Tandem reactions that involve chemoselective Knoevenagel/Perkin condensation-decarboxylation-Heck/Suzuki coupling or Heck-aldol sequences have been achieved. This enabled the first concise and efficient synthesis of several important hydroxy-functionalized compound classes, such as stilbene-cinnamoyl hybrids (potent protein tyrosine phosphatase1B inhibitors), cinnamoyl-cinnamic acid hybrids, asymmetric distyrylbenzenes, and biarylstyrenes. Previously reported synthesis require multiple steps and protection/deprotection manipulations.
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