期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 17, 期 9, 页码 2642-2646出版社
WILEY-BLACKWELL
DOI: 10.1002/chem.201002608
关键词
emeraldicene; Heck reaction; nucleophilic aromatic alkylation; organic acceptor; polycyclic heteroaromatic hydrocarbon
资金
- University of California, Santa Barbara MRL
- Konarka Technologies Inc.
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0840521] Funding Source: National Science Foundation
By understanding the role of DMF as a hydride source via a Pd-catalyzed reaction and switching to CH(3)CN solvent, an efficient route for the synthesis of emeraldicene and some new substituted derivatives is reported with potential application in organic electronics. Additionally, the nucleophilic alkylation of emeraldicene 4a with alkyllithium reagents provides monosubstituted compounds 7a and 7b, the latter crystallizing in columnar stacks, with pi-pi overlap between adjacent molecules in the stack.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据