期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 17, 期 30, 页码 8404-8413出版社
WILEY-BLACKWELL
DOI: 10.1002/chem.201100655
关键词
acetals; aldehydes; heterogeneous catalysis; hydrosilylation; nanoparticles; palladium
资金
- Tekes (Enabling Synthesis Technologies platform)
- University of Jyvaskyla, Department of Chemistry
A highly versatile and efficient hydrosilylation method by palladium nanoparticle catalysis allows the direct and chemoselective synthesis of 1) enolsilanes of high isomeric purity, 2) saturated aldehydes or ketones, or 3) the corresponding saturated acetals from alpha,beta-unsaturated aldehydes or ketones. The choice of the product is determined by simply switching the solvent from THF to mixtures of THF/water or THF/alcohol.
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