期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 17, 期 31, 页码 8604-8608出版社
WILEY-BLACKWELL
DOI: 10.1002/chem.201100442
关键词
acceptors; electrochemistry; fluorenylidenes; fullerenes; polycycles
资金
- Materials Research Laboratory Facilities Network, University of California, Santa Barbara
- Konarka Inc.
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0840521] Funding Source: National Science Foundation
We have designed the synthesis of deconvoluted fullerene derivatives that present an ordered pattern of hexagons and pentagons in the backbone of the molecule. We not only mimicked the fullerene structure in dihedral planes, but also preserved its electron accepting behavior and enlarged its optical absorption. Moreover, very preliminary photoluminescence (PL) quenching experiments also confirmed the potentiality of these materials as acceptors in the field of organic photovoltaics (OPV)s. A brief discussion of the surface morphology, based on AFM analysis, is also presented.
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