期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 17, 期 29, 页码 8066-8070出版社
WILEY-BLACKWELL
DOI: 10.1002/chem.201100929
关键词
alcohols; asymmetric catalysis; FBSM; Morita-Baylis-Hillman reactions; organocatalysis
资金
- NSFC [21072044]
- Henan Province International Cooperation Foundation [104300510062]
- KAUST [4000000076]
Enanatiopure beta-methyl-gamma-monofluoromethyl alcohols were prepared from the allylic alkylation between fluorobis(phenylsulfonyl) methane with Morita-Baylis-Hillman carbonates. The reaction was catalyzed by using the Cinchona alkaloid derivative, (DHQD)(2)AQN. The origin of the stereoselectivity was verified by DFT methods. Calculated geometries and relative energies of various transition states strongly support the observed stereoselectivity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据