期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 16, 期 40, 页码 12244-12254出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201001424
关键词
density functional calculations; dyes/pigments; energy conversion; platinum; sensitizers
资金
- University of Hong Kong
- University Grants Committee Areas of Excellence Scheme [AoE/P-03/08]
- Special Equipment Grant [SEG HKU07]
A series of platinum(II) alkynyl-based sensitizers has been synthesized and found to show light-to-electricity conversion properties. These dyes were developed as sensitizers for the application in nanocrystalline TiO2 dye-sensitized solar cells (DSSCs). Their photophysical and electrochemical properties were studied. The excited-state property was probed using nanosecond transient absorption spectroscopy, which showed the formation of a charge-separated state that arises from the intramolecular photoinduced charge transfer from the platinum(II) alkynylbithienylbenzothiadiazole moiety (donor) to the polypyridyl ligand (acceptor). A lifetime of 3.4 mu s was observed for the charge-separated state. A dye-sensitized solar cell based on one of the complexes showed a short-circuit photocurrent of 7.12 mA cm(-2), an open circuit voltage of 780 mV, and a fill factor of 0.65, thus giving an overall power conversion efficiency of 3.6%.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据