期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 16, 期 18, 页码 5274-5284出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201000470
关键词
C-H activation; homogeneous catalysis; hydroxylation; oxidation; phenols
资金
- Spanish Ministerio de Educacion y Ciencia [CTQ2007-62771/BQU, CTQ2007-65218/BQU]
- CONSOLIDER INGENIO [2010 CSD2007-00006]
- Generalitat Valenciana [GV/2007/036, GV/2007/142, GVPRE/2008/278]
- PROMETEO [2009/039]
- Universidad de Alicante
An overview of the recent bibliography in the transition-metal-catalyzed hydroxylation of aryl derivatives is presented. Two reaction protocols are considered: 1) C-H activation/hydroxylation and, 2) cross-coupling hydroxylation of aryl halides. The achievements and limitations for both procedures are described taking into consideration different metal catalyst/oxidant combinations.
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