期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 16, 期 32, 页码 9789-9795出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201000278
关键词
copper; cyclopropanation; gold; heterogeneous catalysis; metal-organic frameworks
The copper and gold metal organic frameworks (MOFs) [Cu-3(BTC)(2)(H2O)(3)](n), [Cu-3(BTC)(2)] (BTC=benzene-1.3.5-tricarboxylate). and IRMOF-3-SI-Au are active and reusable solid catalysts for the cyclopropanation of alkenes with high chemo- and diastereoselectivities Pus type of material gives better results than previous solid catalysts while working together with the homogeneous catalysts These MOFs can help to budge the gap between homogeneous and heterogeneous catalysis.
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