期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 16, 期 31, 页码 9414-9421出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201000752
关键词
computational chemistry; cyclopropyl probes; reaction mechanisms; singlet oxygen; stereoselectivity
资金
- Foundation for Education and European Culture
- University of Crete [ELKE K.A. 2943]
The mechanism of the singlet oxygen ene reaction has been a subject of renewed interest within the last few years. The main question being whether this reaction proceeds through a concerted mechanism or if it involves discrete intermediates. In general, the majority of experimental and computational studies support a traditional stepwise mechanism involving a perepoxide-like intermediate. In this minireview we highlight the most prominent and recent theoretical, as well as experimental results relating to the challenging mechanism of the singlet oxygen ene oxyfunctionalization.
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