期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 16, 期 39, 页码 12000-12007出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200903263
关键词
cobalt; electrochemistry; hierarchical structures; magnetic properties; solvothermal synthesis; sulfur
资金
- National Basic Research Program of China [2010CB934700]
- International S T Cooperation [2010DFA41170]
- National Natural Science Foundation of China [50732006]
- National Synchrotron Radiation Laboratory (NSRL, Hefei, China)
A simple solvothermal route in a binary solution of triethylenetetramine (TETA) and deionized water (DIW) has been used to synthesize hierarchical hollow Co9S8 microspheres with high surface area (80.38 rn(2)g(-1)). An appropriate volume ratio of TETA:DIW has been found to be essential for the formation of hollow Co9S8 microspheres. The magnetic study indicated that the Co9S8 hollow microspheres are paramagnetic at high temperature and antiferromagnetic at low temperature. The oxygen reduction reaction experiments demonstrated that the onset potential of the Co9S8 sample is 0.88 V, which is comparable to the value predicted for Co9S8 (0.74 V) from the theoretical simulation. The discharge capability of Co9S8 hollow microspheres as cathode materials for lithium ion batteries and their electrocatalytic activity for the oxygen reduction reaction (ORR) have been studied.
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