期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 16, 期 44, 页码 13193-13198出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201001871
关键词
alcohols; alkylation; anilines; iridium; N,P ligands
资金
- NanoCat
The synthesis of eight new iridium complexes containing anionic PN ligands is described These complexes have been investigated as catalysts for amine alkylation reactions, resulting in a highly active catalyst for the selective monoalkylation of anilines with primary alcohols under mild reaction conditions Nearly quantitative conversion was observed at 70 degrees C with a catalyst loading as low as 0 05 mol % iridium
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