期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 16, 期 10, 页码 3215-3221出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200902624
关键词
alkanes; carbocations; isotopic labeling; reaction mechanisms; solid acids
资金
- Locker Hydrocarbon Institute (USC, Los Angeles)
- CNRS
- Ministere de la Recherche
As evidenced by H/D exchange with acidic zeolites, isoalkanes react readily at room temperature whereas linear alkanes do not. The observed regioselectivity of the exchange process demonstrates that the main factor controlling the reaction is not the accessibility to the acid sites, but the intrinsic reactivity of the alkane. The mechanism is best rationalized by classic organic chemistry involving carbocationic intermediates including the Markovnikov rule.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据