期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 15, 期 8, 页码 1893-1900出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200802145
关键词
Diels-Alder reaction; materials science; polymers; reversible cross-linking; thin films
资金
- French Ministere de la Recherche et de la Technologie
Dynamers based oil reversible Diels-Alder chemistry have been obtained and shown to undergo dynamic exchange at room temperature. Their study in solution by small-angle neutron scattering indicated the formation of long and highly flexible chains. Polydispersed molecules gave T-g values below room temperature, permitting the generation of a dynamic elastomer upon introduction of a dynamic cross-linking agent. The use of a system with a low equilibrium constant gives access to materials with interesting self-healing properties.
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