期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 15, 期 28, 页码 6953-6963出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200900361
关键词
arenes; heterogeneous catalysis; hydrogenation; rhodium; ruthenium
资金
- Nagase Science Technology Development Foundation
An efficient and practical arene hydrogenation procedure based on the use of heterogeneous platinum group catalysts has been developed. Rh/C is the most effective catalyst for the hydrogenation of the aromatic ring, which can be conducted in iPrOH under neutral conditions and at ordinary to medium H-2 pressures (< 10 atm). A variety of arenes such as alkylbenzenes, benzoic acids, pyridines, furans, are hydrogenated to the corresponding cyclohexyl and heterocyclic compounds in good to excellent yields. The use of Ru/C, less expensive than Rh/C, affords an effective and practical method for the hydrogenation of arenes including phenols. Both catalysts can be reused several times after simple filtration without any significant loss of catalytic activity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据