期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 15, 期 25, 页码 6175-6185出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200900287
关键词
chromophores; electro-optical absorption measurements; heterocycles; hyper-Raleigh scattering; nonlinear optics
资金
- European Commission [NMP3-CT-2003-505478]
- MIUR-FIRB [RBNE033KMA]
A series of highly efficient and thermally stable second-order non-linear optical (NLO) dipolar donor-auxiliary donor-acceptor chromophores have been synthesised in which a hydrazono group and a pyrrole ring act as donor and auxiliary donor components, respectively. in combination with different aromatic and heteroaromatic acceptors. The new dyes have been systematically investigated by NMR spectroscopy, absorption spectroscopy, NLO measurements and thermal stability Studies. NLO properties have been studied in detail by electro-optical absorption (EOA) and hyper-Rayleigh scattering (HRS) measurements in 1,4-dioxane and DMSO, respectively. The results originating from the two different methods have been compared and analysed in detail. We found that the NLO properties measured by the EOA and HRS methods cot-relate with each other and converge to reveal the dye with the acceptor 2-dicyanomethylene-3-cyano-4,5,5-trimethyl-2,5-dihydrofuran as the most efficient system. The unprecedented combination of it strong donor hydrazono group and the auxiliary donor effects of pi-excessive heteroaromatic rings afforded NLO chromophores with very high values (mu(g)beta(0)(EOA) up to 2038 x 10(-48) esu and beta(HRS) up to 3980 x 10(-30) esu at 1.5 mu m).
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