期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 15, 期 35, 页码 8842-8851出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200900422
关键词
aurophilicity; calixarenes; crown compounds; luminescence; sensors
资金
- University of Hong Kong under the Distinguished Research Achievement Award Scheme
- URC Strategic Research Theme on Molecular Materials
- Research Grants Council of Hong Kong Special Administrative Region. P. R. China [HKU 7050/08P]
Two calixarene-based bis-alkynyl-bridged Au-I isonitrile complexes with two different crown ether pendants, [{calix[4]arene-(OCH2CONH-C6H4C C)(2)}{Au(CNR)}(2)] (R = benzo[15]crown-5 (1): R = benzo[18]crown-6 (2)), together with their related crown-free analogue 3 (R=C6H3-(OMe)(2)-3,4) and a mononuclear gold(I) complex 4 with benzo[15]-crown-5 pendant, have been designed and synthesized, and their photophysical properties have been studied. The X-ray structure of the ligand, calix[4]-arene-(OCH,CONH-C6H4C CH)(2) has been determined. The cation-binding properties of these complexes with various metal ions have been studied using UV/Vis, emission, H-1 NMR, and ESI-MS techniques, and DFT calculations. A new low-energy emission band associated with Au center dot center dot center dot Au interaction could be switched on upon formation of the metal ion-bound adduct in a sandwich fashion.
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