期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 15, 期 45, 页码 12168-12179出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200901486
关键词
auto-tandem catalysis; domino reactions; organocatalysis; tandem catalysis; transition-metal catalysis
资金
- Ministry of Education, Culture, Sports, Science, and Technology, Japan
- Shorai Foundation for Science and Technology
Domino reactions have received great attention as efficient synthetic methodologies for the construction of structurally complex molecules from simple materials in a single operation. Catalysts in domino reactions have also been well studied. In these reactions, a catalyst activates the substrate(s) only once, and the structure of the product is delineated at that time. Recently, the new concept of tandem catalysis in domino reactions, in which catalyst(s) sequentially activate more than two mechanistically distinct reactions, has been proposed. Tandem catalysis is categorized into three subclasses: orthogonal-, auto-, and assisted-tandem catalyses. Auto-tandem catalysis is defined as a process in which one catalyst promotes more than two fundamentally different reactions in a single reactor. An overview of recent and significant achievements in auto-tandem catalysis is presented in this paper.
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