期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 15, 期 11, 页码 2476-2485出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200801968
关键词
anions; conjugation; Group 14 elements; multiple bonds; Si ligands; silicon
资金
- Deutsche Forschungsgemeinschaft (DFG)
- Fonds der Chemischen Industrie (FCI)
- Karl-Winnacker-Fonds of the Aventis Foundation
- Dr. Otto Rohm-Gedachtnisstiftung.
Anionic compounds capable of transferring a silicon double bond are summarized following an introduction to the differences between alkenes and their heavier homologues. The main focus is on reagents with Si=Si moieties and their applications towards main-group and transition-metal electrophiles, as well as their reactivity towards organic compounds, but a few recently reported derivatives with Si=C and Si=P bonds are also included.
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