期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 15, 期 41, 页码 10924-10929出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200900841
关键词
fullerenes; macrocycles; porphyrinoids; template synthesis; supramolecular chemistry
资金
- Ministry of Science and Higher Education [PBZ-KBN-118rF09/2004]
Insertion of PCl3 into 5,10,15,20-tetraaryl-21-telluraporphyrin leads to a phosphorus complex of N-fused dihydrotelluraporphyrin with an inverted tellurophene ring. Its CNN coordination core places the macrocycle in the family of contracted carbaporphyrinoids. A cycle of direct transformations affords an elegant triangle of three mutually convertible N-fused porphyrinoids, with distinct spectroscopic features: antiaromatic, nonaromatic and aromatic. The nonaromatic species has a dome shaped skeleton which forms in the solid state a ball and socket structure with C-60.
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