期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 16, 期 3, 页码 890-898出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200901668
关键词
alkyl chains; conformational polymorphism; crystallochromy; exciton coupling; tetracenes
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [20550128]
We synthesized a series of 1,4,7,10-tetraalkyltetracenes using a new 2,6-naphthodiyne precursor and 2,5-dialkylfurans as starting materials (alkyl=methyl to hexyl). Surprisingly, the solid-state color of the tetracenes ranges through yellow, orange, and red. Both yellow and red solids are obtained for the butyl derivative. Optical properties in solution show no marked differences; however, those in the solid state show characteristics that vary with alkyl side-chain length: methyl, propyl, and pentyl derivatives are orange; ethyl and butyl derivatives are yellow; and another butyl and hexyl derivative are red. X-ray analyses reveal that the molecular structures are planar, semi-chair, or chair forms; the chair form takes a herringbone-like arrangement and the other forms take slipped parallel arrangements. The mechanism of crystallochromy is discussed in terms of molecular structure, crystal packing, and calculations that take account of exciton coupling.
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