期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 15, 期 30, 页码 7268-7276出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200900607
关键词
asymmetric catalysis; atropisomerism; chirality; helical structures; heterocycles
资金
- Florida Department of Health [07 KN-12]
- American Cancer Society [IRG-98-277-07]
- Sylvester Comprehensive Cancer Center
- University of Miami
Optically active chiral alkyl chlorides are valuable compounds because of their bioactivity and versatile synthetic utility. Accordingly, the ring opening of epoxides with a chloride nucleophile stands as an important goal in asymmetric catalysis. We describe herein recent advances in the design and development of chiral pyridine N-oxide catalysts for the enantioselective synthesis of chlorohydrins.
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