期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 15, 期 32, 页码 7808-7821出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200900707
关键词
cycloaddition; glycosidase inhibitors; iminosugars; nitrones; pyrrolizidines
资金
- Ministry of Instruction, University and Research (MIUR, Rome)
- PRIN Projects
The synthesis of polyhydroxylated indolizidines and pyrrolizidines belonging to the class of imino-sugars, endowed with a vast and assorted biological activity, can be achieved in a straightforward manner by a general strategy consisting of a highly stereoselective 1,3-dipolar cycloaddition of polyhydroxylated pyrroline-N-oxides followed by simple transformations of the isoxazolidine adducts. The strategy allows the complete control of the relative and absolute stereochemistry of the numerous stereogenic centers decorating these compounds.
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