期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 15, 期 48, 页码 13456-13465出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200902031
关键词
carbohydrates; helical structures; salphen; supramolecular chemistry; zinc
资金
- Natural Sciences and Engineering Research Council (NSERC) of Canada
Metallosalphen complexes with peripheral glucose and galactose substituents were synthesized and characterized. Their self-assembled supramolecular structures were then studied with transmission electron microscopy (TEM), scanning electron microscopy (SEM) and atomic force microscopy (AFM). It was found that all of the complexes displayed aggregation in the solid-state. Zinc-salphen complexes showed a remarkably homogeneous helical nanofibrillar morphology, whereas the other metal complexes only displayed micron-sized clusters.
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