期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 14, 期 11, 页码 3380-3390出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200701348
关键词
ceria; cerium; crystal growth; nanostructures; self-assembly
Uniform CeO2 nanoflowers were synthesized by rapid thermolysis of (NH4)(2)Ce(NO3)(6) in oleic acid (OA)/oleylamine (OM), by a unique 3D oriented-attachment mechanism. CeO2 nanoflowers with controlled shape (cubic, four-petaled, and starlike) and tunable size (10-40 nm) were obtained by adjusting the reaction conditions including solvent composition, precursor concentration, reaction temperature, and reaction time. The nanoflower growth mechanism was investigated by in situ electrical conductance measurements, transmission electron microscopy, and UV/Vis spectroscopy. The CeO2 nanoflowers are likely formed in two major steps, that is, initial formation of ceria cluster particles capped with various ligands (e.g., OA, OM, and NO3-) via hydrolysis of (NH4)(2)Ce(NO3)(6) at temperatures in the range 140-220 degrees C, and subsequent spontaneous organization of the primary particles into nanoflowers by 3D oriented attachment, due to a rapid decrease in surface ligand coverage caused by sudden decomposition of the precursor at temperatures above 220 degrees C in a strong redox reaction. After calcination at 400 degrees C for 4 h the 33.8 nm CeO2 nanoflowers have a specific surface area as large as 156 m(2)g(-1) with high porosity, and they are highly active for conversion of CO to CO2 in the low temperature range of 200-400 degrees C. The present approach has also been extended to the preparation of other transition metal oxide (CoO, NiO, and CuOx) nanoflowers.
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