期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 14, 期 12, 页码 3759-3764出版社
WILEY-BLACKWELL
DOI: 10.1002/chem.200701982
关键词
asymmetric catalysis; boronic acids; carbenes; Michael addition; palladium
Axially chiral cis-chelated bidentate bis(N-heterocyclic carbene)-palladium(II) complexes with two weakly coordinating carboxylate ligands are effective catalysts for the asymmetric conjugate addition of arylboronic acids to cyclic enones, producing the corresponding adducts in moderate-to-high yields and with good-to-high enantioselectivities, in most cases under mild conditions.
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