期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 14, 期 35, 页码 11167-11173出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200800828
关键词
ab initio calculations; energetic materials; ionic liquids; lanthanides; nitrate complexes
资金
- Defense Threat Reduction Agency [HDTPA1-07-1-0024]
- National Science Foundation [CHE-0315275]
- Office of Naval Research [N00014-06-11032]
- Department of Defense High Performance Computing Modernization Program
Energetic ionic liquids based on anionic lanthanide nitrate complexes Cat(3)(+)[Ln(NO3)(6)](3-), where Cat(+) is guanidinium, 4-aminotriazolium, 4-amino-1-methyltriazolium, 4-amino-1-ethyltriazolium, 4-amino-1-butyltriazolium, 1,5-diaminotetrazolium, and 1,5-diamino-4-methyltetrazolium, were prepared. The hexanitratolanthanate (-cerate) salts with the last two cations, which are the first CO-balanced energetic ionic liquids that are stable to hydrolysis and air, have impact sensitivities of about 27 J. These ionic liquids were obtained by an environmentally friendly, simple method using nitrate-containing precursors. All salts were fully characterized by IR and NMR spectroscopy, elemental analysis, and determination of thermal stability, phase behavior, density, and water content. According to theoretical calculations, these new compounds have potential as propellants.
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