期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 14, 期 32, 页码 9816-9829出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200800674
关键词
confinement effects; host-guest systems; mesoporous materials; nanochemistry; surface design
资金
- Deutsche Forschungsgemeinschaft (DFG)
The everyday routine of most chemists is dictated by large numbers. The chemical rules for ensembles of molar size (N approximate to N-A = 6.022 x 10(23)) are well known and can be understood in most cases by using Boltzmann distribution. It is an interesting question how a small ensemble of a chemical system behaves and if it differs from the respective large-ensemble counterpart. The experimental approach presented in the current paper involves the division of a macroscopic volume into compartments that contain only a small number of reactants. The compartments represent the pores of tailor-made nanoporous materials.
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