期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 14, 期 33, 页码 10415-10422出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200801321
关键词
alkoxides; bicyclic; carbenes; uranium; uranyl; yttrium
资金
- EPSRC
- Alexander von Humboldt Foundation
- University of Edinburgh
A new and modular route to bidentate ligands that combines an alkoxide with a saturated backbone N-heterocyclic carbene (NHC) is presented. The bi(heterocyclic) compounds are formally the addition product of a saturated NHC and the alcohol group of the N-functionalised arm. Using these Compounds, the synthesis and structural characterisation of the first electro-positive metal complexes of saturated N-heterocyclic carbenes has been achieved, and examples Structurally characterised for the yttrium(III) and the uranyl [UO2](2+) cations.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据