期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 14, 期 32, 页码 10141-10148出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200800558
关键词
C-C coupling; green chemistry; polymers; recycling; till
资金
- Spanish MEC [CT02007-67411/BQU]
- INTECAT [CSD2006-0003]
- Junta de Castilla y Leon [VA117A06]
New functionalized polynorbornenes have been obtained in good yields by vinylic copolymerization of norbornene with a (norbornenyl)Sn-Bu2Cl monomer, catalyzed by [Ni(C6F5)(2)(SbPh3)(2)]. Subsequent functionalization produces a wide variety of polymers with different -SnBu2R groups (R = aryl, vinyl, alkynyl). The polymers can be used as R-transfer reagents in Stille couplings, thereby providing easy workup and separation of the polymeric tin byproducts from the coupling products. Tin contents of around 0.05 wt% are found in the Stille products. The stannylated polymers can be recycled and reused with good efficiency.
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