期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 14, 期 13, 页码 4060-4067出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200701911
关键词
boronic acid; lactate; ligands; receptors; sensors
资金
- Biotechnology and Biological Sciences Research Council Funding Source: Medline
Boronic acids have been used as receptors for the detection of diols and a-hydroxy acids. The incorporation of 3-acrylamide phenyl boronic acid (3-APB) into a hydrogel generates a suitably responsive and fully reversible holographic sensor for L-lactate, However, it was also found that the use of 3-APB resulted in the sensor being responsive towards a number of other compounds containing two hydroxy groups. This report details the further investigation into the reaction between L-lactate and three boronic acid-based receptors, both in the holograms and in solution, in order to establish the mechanism of binding. A novel boronate receptor is proposed based on this understanding.
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