期刊
CHEMISTRY OF NATURAL COMPOUNDS
卷 50, 期 3, 页码 417-419出版社
SPRINGER
DOI: 10.1007/s10600-014-0974-0
关键词
Echinothrix diadema; 6,8,9-trihydroxy-2-methyl-2H-naphtho[2,3-b]pyran-5,10-dione; pyranonaphthazarins; tautomers
资金
- Interdisciplinary Integrated Project of the Far-East, Siberian [12-II-SU-05-006]
- Interdisciplinary Integrated Project of the Far-East, Ural Branches [12-II-SU-05-006]
- Interdisciplinary Integrated Project of the Far-East, RAS [12-II-SU-05-006]
- RAS Presidium (Molecular and Cellular Biology Program)
6,8,9-Trihydroxy-2-methyl-2H-naphtho[2,3-b]pyran-5,10-dione, a pigment of Echinothrix diadema, was synthesized. It existed as a mixture of two tautomers in CHCl3 solution according to IR spectroscopy. Its analogs 6,9-dihydroxy-2-methyl-2H-naphtho[2,3-b]pyran-5,10-dione and 6,9-dihydroxy-2-methyl-7,8-dichloro-2H-naphtho[2,3-b]pyran-5,10-dione were synthesized.
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