期刊
CHEMISTRY OF MATERIALS
卷 30, 期 19, 页码 6777-6787出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.8b02679
关键词
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资金
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education, Science, and Technology of Korea [NRF-2017R1A2A2A05069634, NRF-2015M3D1A1069713]
- State Committee on Science and Technology of the Republic of Belarus
- International Research & Development Program of the National Research Foundation of Korea (NRF) - Ministry of Science and ICT of Korea [NRF-2017K1A3A1A30084795]
- National Research Foundation of Korea [2017K1A3A1A30084795, 2015M3D1A1069713, 2017R1A2A2A05069634] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Zinc-ion batteries are emerging as next-generation rechargeable batteries that can operate in aqueous electrolytes. We first examine the feasibility of open-structured VO2(B) as a Zn2+ intercalation host. A bond-valence sum energy map predicts that four Zn2+-tion sites (Zn-C, Zn-A1, Zn-A2, and Zn-C) can exist in the structure. Using first-principles calculations, we verified that 0.5 mol of Zn2+ ions can be reversibly (de)intercalated with an average voltage of similar to 0.61 V (vs Zn2+/Zn), which is comparable with the experimental results. The specific capacity of VO2(B) at 50 mA g(-1) is maintained up to similar to 365 mAh g(-1) corresponding to the storage capacity of similar to 0.57 mol of Zn2+ ions in the framework of VO2(B), and its redox reaction occurs at similar to 0.61 V. The high capacity is maintained for 200 cycles, with capacity retention of 80% (288 mAh g(-1)). Moreover, the capacity delivered by the VO2(B) electrode is stable even with cycling at a rate of SC (1750 mA g(-1)) at approximately 110 mAh g(-1). This high-power capability of VO2 is supported by the theoretical approach based on first-principles calculation, which shows the activation barrier for Zn2+ diffusion in the VO2(B) structure. These findings demonstrate the potential of open-structured VO2(B) as a new candidate material.
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