期刊
CHEMISTRY OF MATERIALS
卷 26, 期 11, 页码 3403-3410出版社
AMER CHEMICAL SOC
DOI: 10.1021/cm500575q
关键词
-
We describe a V2O5 polysulfide anion barrier for a Li-S battery containing a Li metal anode, an organic solvent-based electrolyte, and a nanostructured carbon-sulfur composite cathode that cycles without degradation from dissolution of soluble polysulfide anions. Degradation is prevented by the micrometer-scale V2O5 layer that physically isolates the anode and cathode electrolytes, thus blocking diffusion of dissolved polysulfide anions while permitting solid-state transport of Li+ cations. This divided cell architecture eliminates the interaction of soluble polysulfide with the Li anode. Mechanical integrity of the thin V2O5 layer is achieved by depositing the layer on a commercial polymeric battery separator. In addition, the isolated cathode electrolyte is optimized by the intentional addition of Li2S8, which suppresses redistribution of sulfur within the nanostructured carbon-sulfur composite cathode. A 5 mA h pouch cell this design has been cycled >300 times over similar to 1 year without noticeable degradation at capacities of 800 mA h g-sulfur(-1).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据