期刊
CHEMISTRY OF MATERIALS
卷 26, 期 15, 页码 4354-4360出版社
AMER CHEMICAL SOC
DOI: 10.1021/cm500786a
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资金
- National Natural Science Foundation of China [51273158, 21303131]
- Natural Science Basis Research Plan in Shaanxi Province of China [2012JQ6003, 2013KJXX-49]
- Ph.D. Programs Foundation of Ministry of Education of China [20120201120048]
- Program for New Century Excellent Talents in University [NCET-13-0449]
- Fundamental Research Funds for the Central Universities
One-dimensional hierarchical nanostructure of NiCo2O4 nanosheets@halloysite nanotubes was successfully prepared through a facile coprecipitation method followed by a thermal annealing treatment. The microstructure and chemical composition of NiCo2O4 nanosheets@halloysite nanotubes are investigated by SEM, TEM, HRTEM, XRD, and XPS. The specific capacitance of the unique NiCo2O4 nanosheets@ halloysite nanotubes is 1728 F g(-1) at the end of 8600 cycles when the charge-discharge current density is 10 A g(-1) leading to only 5.26% capacity loss. Broadly, the as-obtained NiCo2O4 nanosheets@halloysite nanotubes reveal ultrahigh capacitance and remarkable cycling stability in virtue of the ultrathin and hierarchical nanosheets and intense cation/anion exchange performance of halloysite.
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