期刊
CHEMISTRY OF MATERIALS
卷 26, 期 10, 页码 3289-3294出版社
AMER CHEMICAL SOC
DOI: 10.1021/cm501110v
关键词
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资金
- Basque Government through the Etortek project energiGUNE'10
- European Union [312483 - ESTEEM2]
NaFePO4 is known as a promising intercalation cathode material for sodium-ion batteries. During the electrochemical reaction, an intermediate phase forms with a composition close to Na approximate to 2/3FePO4, whose crystal structure is defined with a supercell that results from both Na/vacancy and charge ordering. In this work, we present a detailed study of this superstructure through synchrotron powder X-ray diffraction and electron microscopy studies.
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