期刊
CHEMISTRY OF MATERIALS
卷 25, 期 11, 页码 2309-2318出版社
AMER CHEMICAL SOC
DOI: 10.1021/cm400911j
关键词
core/shell nanoparticles; self-assembly; stimuli-responsive materials; photonic crystals; polymeric materials
资金
- Landesoffensive zur Entwicklung Wissenschaftlich-okonomischer Exzellenz (LOEWE Soft Control)
A new strategy to achieve easily scalable triple stimuli-responsive elastomeric opal films for applications as stretch-tunable photonic band gap materials is reported. Novel monodisperse highly functional core-interlayer-shell beads are obtained by semicontinuous emulsion polymerization featuring a temperature-sensitive fluorescent rhodamine dye either locally restricted in the core or the shell of prepared beads. After extrusion and compression molding, homogeneous elastomeric opal films with fascinating stretch-tunable and temperature-dependent fluorescent properties can be obtained. Applying strains of only a few percent lead to significant blue shift of the reflected colors making these films excellent candidates for applications as deformation sensors. Higher strains up to 90% lead to a tremendous Bragg reflection color change caused by transition from the (111) to the (200) lattice plane. The well ordered opaline structure with its stop band at the emission frequency of the incorporated fluorescent dye shows remarkable angle dependent fluorescence suppression. Herein described elastomeric opal films can be valuable in a wide range of applications such as rewritable 3D optical data storage, tunable laser action, and sensing materials.
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