期刊
CHEMISTRY OF MATERIALS
卷 25, 期 18, 页码 3589-3596出版社
AMER CHEMICAL SOC
DOI: 10.1021/cm401130n
关键词
naphthalenediimide; ambipolar transistors; complementary-like inverters; vinyl linkages; high performance
资金
- National Natural Science Foundation of China [20825208, 61101051, 51233006, 21021091]
- Major State Basic Research Development Program [2011CB808403, 2011CB932303]
We report the synthesis of two novel donoracceptor copolymers poly{[N, N'-bis(alkyl)-1,4,5,8-naphthalene diimide-2,6-diyl-alt-5,5'-di(thiophen-2-yl)-2,2'-(E)-2-(2-(thiophen-2-yl)vinyl)thiophene]} (PNVTs) based on naphthalenediimide (NDI) acceptor and (E)-2-(2-(thiophen-2-yl)vinyl)thiophene donor. The incorporations of vinyl linkages into polymer backbones maintain the energy levels of the lowest unoccupied molecular orbits at -3.90 eV, therefore facilitating the electron injection. Moreover, the energy levels of the highest occupied molecular orbits increase from -5.82 to -5.61 eV, successfully decreasing the hole injection barrier. Atomic force microscopy measurements indicate that PNVTs thin films exhibit larger polycrystalline grains compared with that of poly{[N, N'-bis(2-octyldodecyl)-1,4,5,8-naphthalene diimide-2,6-diyl]-alt- 5,5'-(2,2'-bithiophene)} [P(NDI2OD-T2)], consistent with the stronger pi-pi stacking measured by grazing incidence X-ray scatting. To optimize devices performance, field-effect transistors (FETs) with three devices configurations have been investigated. The results indicate that the electron mobility of the vinyl-containing PNVTs exhibit about 35 times higher than that of P(NDI2OD-T2). Additionally, the vinyl-linkages in PNVTs remarkably enhance ambipolar transport of their top-gate FETs, obtaining high hole and electron mobilities of 0.30 and 1.57 cm(2) V1 s1, respectively, which are among the highest values reported to date for the NDI-based polymers. Most importantly, ambipolar inverters have been realized in ambient, exhibiting a high gain of 155. These results provide important progresses in solution-processed ambipolar polymeric FETs and complementary-like inverters.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据