期刊
CHEMISTRY OF MATERIALS
卷 24, 期 22, 页码 4424-4433出版社
AMER CHEMICAL SOC
DOI: 10.1021/cm3028115
关键词
combinatorial polymer library; silver nanoplates; seed-mediated growth; surface plasmon resonance; defect structure
资金
- second stage of the Brain Korea 21 Project
- National Research Foundation of Korea [2012R1A1A2A10042814]
- National Research Foundation of Korea [2012R1A1A2A10042814] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
We employ a combinatorial library approach to control the shape of the silver nanostructures by regulating the structure of their seeds. Twenty-four polymers are investigated in detail with respect to their functionalities, chemical structures, molecular weights, and charges, each of which turns out to play significant roles in synthesizing high-quality silver nanoplates at room temperature in a fast manner. A mechanism depicting the exceptionally stable seed structures 'stitched' by polymer threads is proposed, which clearly explains the experimental observations.
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