期刊
CHEMISTRY OF MATERIALS
卷 22, 期 17, 页码 5054-5064出版社
AMER CHEMICAL SOC
DOI: 10.1021/cm101634k
关键词
-
资金
- National Natural Science Foundation of China [50773038, 20974093]
- National Basic Research Program of China (973 Program) [2007CB936000]
- Fundamental Research Funds for the Central Universities [2009QNA4040]
- Qianjiang Talent Foundation of Zhejiang Province [2010R10021]
- Foundation for the Author of National Excellent Doctoral Dissertation of China [200527]
A unified approach to covalently functionalize graphene nanosheets based on nitrene chemistry is reported. This strategy is simple and efficient, allowing various functional moieties (e.g., hydroxyl, carboxyl, amino, bromine, long alkyl chain, etc.) and polymers (e.g., poly(ethylene glycol), polystryene) to covalently and stably anchor on graphene to produce single-layer functionalized graphene from graphene oxide in a one-step reaction. The structure and morphology of nanosheets are characterized using microscopy (AFM, SEM, TEM), spectroscopy (FTIR, XPS, Raman), thermal gravimetric analysis (TGA), and X-ray diffraction (XRD) measurements. The resulting functionalized graphene nanosheets are electrically conductive, readily dispersible in solvents and easily processable, making them promising candidates for further modification and applications such as nanohybrids, and polymer composites, etc. The presented work provides a general methodology to prepare individually dispersed graphene nanosheets with various functionalizations and properties, paving the way for the synthesis and applications of functionalized graphene materials.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据