期刊
CHEMISTRY OF MATERIALS
卷 22, 期 8, 页码 2597-2607出版社
AMER CHEMICAL SOC
DOI: 10.1021/cm903664g
关键词
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资金
- European Science Foundation
- Council for Chemical Sciences of The Netherlands Organization for Scientific Research (NWO-CW)
- Royal Netherlands' Academy for Arts and Sciences
- Technology Foundation STW
- EC Marie Curie ITN-SUPERIOR [PITN-GA-2009-238177]
- Engineering and Physical Sciences Research Council (EPSRC, UK)
We describe the design and synthesis of carbazole functionalized isocyanides and the detailed investigation of their properties. Characterization by solid state NMR, CD, and IR spectroscopic techniques reveals that the polymer has a well-defined helical architecture. Surface-initiated polymerization of the isocyanide monomers onto various surfaces was carried out to give polymer brushes up to 150 nm thick. Insights into the electronic properties of the materials were obtained by Kelvin probe force microscopy (KPFM) and electroabsorption studies
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