期刊
CHEMISTRY OF MATERIALS
卷 21, 期 14, 页码 3136-3142出版社
AMER CHEMICAL SOC
DOI: 10.1021/cm900395k
关键词
-
资金
- Natural Science Foundation of China [10774118, 40830744, 50701029]
- Shanghai Pujiang Program [07pj14042]
- Shanghai Leading Academic Discipline Project [S30109]
- [NCET-05-0434]
Graphene has aroused intensive interest because of its unique structure, superior properties, and various promising applications. Graphene nanostructures with significant disorder and defects have been considered to be poor materials because disorder and defects lower their electrical conductivity. In this paper, we report that highly disordered graphene nanosheets can find promising applications in high-capacity Li ion batteries because of their exceptionally high reversible capacities (794-1054 mA h/g) and good cyclic stability. To understand the Li storage mechanism of graphene nanosheets, we have prepared graphene nanosheets with structural parameters tunable via different reduction methods including hydrazine reduction, low-temperature pyrolysis, and electron beam irradiation. The effects of these parameters on Li storage properties were investigated systematically, A key structural parameter, Raman intensity ratio of D bands to G bands, has been identified to evaluate the reversible capacity. The greatly enhanced capacity in disordered graphene nanosheets is suggested to be mainly ascribed to additional reversible storage sites such as edges and other defects.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据