期刊
CHEMISTRY OF MATERIALS
卷 21, 期 1, 页码 186-193出版社
AMER CHEMICAL SOC
DOI: 10.1021/cm801441c
关键词
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资金
- New Energy and Industrial Technology Development Organization [04A32502]
- Research and Development in a New Interdisciplinary Field Based on Nanotechnology
- Materials Science programs of the Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan
- Japan Society for the Promotion of Science (JSPS) [18206081]
- Grants-in-Aid for Scientific Research [18206081] Funding Source: KAKEN
Sulfonic acid group (SO3H)-bearing amorphous carbon/mesoporous silica composites were studied for use as solid acid catalysts. Sugar-derived amorphous carbon with SO3H cannot catalyze hydrophobic acid-catalyzed reactions, such as the dimerization of alpha-methyl styrene, because of the small surface area. However, SO3H-bearing sugar-derived amorphous carbon supported on mesoporous silica exhibits remarkable catalytic performance for the dimerization of alpha-methylstyrene. Under optimal conditions, the selectivity of the composite catalysts for unsaturated dimers exceeds 98%. Structural and reaction analyses revealed that SO3H-bearing carbon particles with large surface areas are formed in the mesopores and prevent intramolecular Friedel-Crafts alkylation, resulting in high catalytic activity.
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