期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 50, 页码 15074-15078出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201507770
关键词
BN-heterocycles; BN-pyrenes; exciton-driven elimination; organic light-emitting diodes; solid-state reactions
资金
- Natural Sciences and Engineering Research Council of Canada
- Natural Science Foundation of China
- JSPS
- Beijing Institute of Technology
New BN-heterocyclic compounds have been found to undergo double arene photoelimination, forming rare yellow fluorescent BN-pyrenes that contain two B N units. Most significant is the discovery that the double arene elimination can also be driven by excitons generated electrically within electroluminescent (EL) devices, enabling the in situ solid-state conversion of BN-heterocycles to BN-pyrenes and the use of BN-pyrenes as emitters for EL devices. The in situ exciton-driven elimination (EDE) phenomenon has also been observed for other BN-heterocycles.
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