Mixing of [(PBP)PtCl] complex with 1-decene and H2O afforded isomerized alkenes. Deuterium-labeling experiment indicated the catalytically active hydride species for alkene isomerization formed from water and [(PBP)Pt] complex. Reaction of [(PBP)PtNTf2] with H2O gave a platinum hydride complex having PNNP ligand with a loss of boron atom, but the resulting complex showed low catalytic activity. Two types of cationic platinum hydride complexes were suggested as active species for alkene isomerization.
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