期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 25, 页码 7303-7307出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201501855
关键词
halogen bonds; hydrogen bonds; resorcinarenes; self-assembly; supramolecular chemistry
资金
- Academy of Finland [265328, 263256, 258653]
- University of Jyvaskyla
Iodine (I-2) acts as a bifunctional halogen-bond donor connecting two macrocyclic molecules of the bowl-shaped halogen-bond acceptor, N-cyclohexyl ammonium resorcinarene chloride 1, to form the dimeric capsule [(1,4-dioxane) 3@I-2(I-2)(2)]. The dimeric capsule is constructed solely through halogen bonds and has a single cavity (V=511 angstrom(3)) large enough to encapsulate three 1,4-dioxane guest molecules.
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