期刊
CHEMISTRY LETTERS
卷 43, 期 7, 页码 1143-1145出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.140393
关键词
-
资金
- JSPS from MEXT, Japan [25620050]
- [2105]
- Grants-in-Aid for Scientific Research [21106012, 25620050] Funding Source: KAKEN
Tetrakis(4-methoxyphenyl)anthraquinodimethane 1(b) with a bent geometry undergoes reversible redox interconversion with twisted dication 1(t)(2+) exhibiting a vivid change in color (electrochromism) accompanied by a drastic structural change. Electrochemical oxidation of bianthraquinodimethane 2(b) with a doubly bent structure to bianthrylidene-type twisted dication 2(t)(2+) proceeded smoothly, whereas the reverse conversion was less effective because 2(t)(2 center dot) generated upon reduction of 2(t)(2+) is a long-lived species to undergo side reactions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据