期刊
CHEMISTRY LETTERS
卷 43, 期 3, 页码 334-336出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.130983
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资金
- Cabinet Office, Government of Japan
Rhenium oxide-modified Ir/SiO2 (Ir-ReOx/SiO2) catalyst shows high activity and selectivity for the dehydrogenation of trans-1,2-cyclohexanediol to 2-hydroxycyclohexanone in water solvent under Ar. Linear vicinal diols bearing two secondary hydroxy groups or both a primary hydroxy group and a secondary hydroxy group can also be transformed to the corresponding alpha-hydroxy ketones in high selectivities. Ir-ReOx/SiO2 can be reused at least four times without loss of activity and selectivity.
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